Abstract
The formation and solvent extraction of new ion-association complexes between anionic chelat of niobium(V) with 2,4-dihydroxythiophenol (DHTP) and hydrophobic amines (HAs). The HAs were aniline (An), N-methylaniline (MAn), N,N-dimethylaniline (DAn). The optimum conditions for the extraction of mixed ligand complexes (MLC) (organic solvent, extraction time, acidity of the aqueous phase, concentration of reagents), some key constants {association constant (β), extraction constant (Kex)} and analytical characteristics were determined. The molar absorptivities of MLC were calculated ε =(3.5-3.9) × 104 L mol–1 cm–1 . The Beer’s law was applicable in the range of 2.2-100 μg/mL.
Ali Z. Zalov. (2015) Complex Formation and Liquid-Liquid Extraction in the Niobium(V) – 2,4-Dihydroxythiophenol–Hydrophobic Amines System, Pakistan Journal of Analytical & Environmental Chemistry, Volume 16, Issue 2.
-
Views
1065 -
Downloads
4
Article Details
Volume
Issue
Type
Language
